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The “NanoCRHEAtion” group was born in 2007 with the aim of exploiting CRHEA’s long expertise in the field of widebandgap semiconductors, namely GaN, ZnO, and their related alloys (AlGaN-InGaN and ZnCdO-ZnMgO). Our research is focused on the growth, by molecular beam epitaxy (MBE) and metalorganic vapour phase epitaxy (MOVPE), of ordered nanostructures for use in photonic and electronic applications such as single photon emitters, microcavities, waveguides or high electron mobility transistors.

Figure 1. Periodically poled (PePo) GaN film for nonlinear optical applications
(Image from reference: S. Pezzagna, P. Vennéguès, N. Grandjean, A. D. Wieck and J. Massies, Appl. Phys. Lett. 87, 062106 (2005)).


Most of these applications will require a regular arrangement of the nanostructures, which we achieve by nanosphere lithography, by e-beam patterning of the substrate and subsequent replication or by self organization phenomena at substrate steps (see Figure 2). Thus, our methodology does not oppose the bottom-up approach against the top-down one, but rather finds itself at the convergence of both approaches and makes use of their particular advantages.

 

 
 
 
Figure 2. Different methods employed in CRHEA for obtaining nanostructures exhibiting long range order: (a) Nanosphere lithography, (b) e-beam patterned Si substrate and (c) self-organization of GaN quantum dots (Image (c) from reference: S. Vezian, A. Le Louarn and J. Massies, J. of Crystal Growth 303, 419 (2007))
 

 

This same philosophy, based on the use of traditionally competing techniques, has led us to combine the growth of nanostructures by MBE and MOCVD. These two techniques have enabled in the past the development of quantum heterostructures with extremely abrupt interfaces and controlled doping levels. These characteristics will be employed for tuning the optical and electrical properties of the nanostructures along their axial and radial directions. The control of the composition and doping profile together with the growth of defect-free objects, will allow enhancing the nanostructures performances with respect to their thin film or bulk counterparts. Furthermore, defect-free nanostructures will be used as seeds for obtaining defect-free bulk objects, thereby closing down the gap between Nanotechnology and Microelectronics.
Figure 3. GaN film regrown on top of GaN nanocolumns (Image from reference: Z. Bougrioua et al., J. of Crystal Growth, in press)
 

The structural characterization of the resulting nanostructures is carried out by scanning electron microscopy, atomic force microscopy, scanning tunnelling microscopy and transmission electron microscopy. For the optical characterization we have photoluminescence (PL), selective PL and electroluminescence facilities, while for the electrical characterization we have I-V, C-V and Hall effect capabilities. Finally, CRHEA has a clean room suited for advance processing and demonstration of device performances.

Figure 4. AFM topographic and zenithal images of CdTe micropyramids analysed by Nanogoniometry (Images from reference E. Palacios-Lidon, L. Guanter, J. Zuniga-Perez, V. Munoz Sanjose, and J. Colchero, Small 3, 474 (2007)).

However, we believe that to develop still further the fields of Nanoscience and Nanotechnology we need to bring together scientists from different laboratories as well as from different research fields, so do not hesitate to contact us if you feel we can develop a joint activity.

NanoCRHEAtion

Last 10 publications of NanoCRHEAtion :

Polariton lasing in a hybrid bulk ZnO microcavity
T. Guillet, M. Mexis, J. Levrat, G. Rossbach, C. Brimont, T. Bretagnon, B. Gil, R. Butté, N. Grandjean, L. Orosz, F. Réveret, J. Leymarie, J. Zúñiga-Pérez, M. Leroux, F. Semond, and S. Bouchoule
Appl. Phys. Lett., 99, 161104, (2011) - Papier régulier
 
AlN photonic crystal nanocavities realized by epitaxial conformal growth on nanopatterned silicon substrate
D. Néel, S. Sergent, M. Mexis, D. Sam-Giao, T. Guillet, C. Brimont, T. Bretagnon, F. Semond, B. Gayral, S. David, X. Checoury, P. Boucaud
Appl. Phys. Lett., 98, 261106, (2011) - Papier régulier
 
Laser emission with excitonic gain in a ZnO planar microcavity
T. Guillet, C. Brimont, P. Valvin, B. Gil1, T. Bretagnon, F. Médard, M. Mihailovic, J. Zúñiga-Pérez, M. Leroux, F. Semond, and S. Bouchoule
Appl. Phys. Lett., 98, 211105 , (2011) - Papier régulier
 
On the polarity of GaN micro- and nanowires epitaxially grown on sapphire (0001) and Si(111) substrates by metal organic vapor phase epitaxy and ammonia-molecular beam epitaxy
B. Alloing, S. Vézian, O. Tottereau, P. Vennéguès, E. Beraudo, and J. Zúñiga-Pérez
Appl. Phys. Lett., 98, 011914, (2011) - Papier régulier
 
Influence of the excitonic broadening on the strong light-matter coupling in bulk zinc oxide microcavities
F. Médard, D. Lagarde, J. Zúñiga-Pérez, P. Disseix, M. Mihailovic, J. Leymarie, E. Frayssinet, J. C. Moreno, F. Semond, M. Leroux, and S. Bouchoule
J. Appl. Phys., 108, 043508, (2010) - Papier régulier
 
Two-dimensional confined photonic wire resonators: strong light-metter coupling
R. Schmidt-Grund, H. Hilmer, A. Hinkel, C. Sturm, B. Rheinlander, V. Gottschalch, M. Lange, J. Zúñiga-Pérez, and M. grundmann
Phys. Stat. Sol. B, 247, 1351, (2010) - Papier régulier
 
Relaxation and emission of Bragg-mode and cavity-mode polaritons in a ZnO microcavity at room temperature
S. Faure, C. Brimont, T. Guillet, T. Bretagon, B. Gil, F. Médard, D. Lagarde, P. Disseix, J. Leymarie, J. Zúñiga-Pérez, M. Leroux, E. Frayssinet, J. C. Moreno, F. Semond, and S. Bouchoule
Appl. Phys. Lett., 95, 121102, (2009) - Papier régulier
 
Experimental observation of strong light-matter coupling in ZnO microcavities: Influence of large excitonic absorption
F. Medard, J. Zúñiga-Pérez, P. Disseix, M. Mihailovic, J. Leymarie, A. Vasson, F. Semond, E. Frayssinet, J. C. Moreno, M. Leroux, S. Faure, T. Guillet
Phys. Rev. B, 79, 125302, (2009) - Papier régulier
 
Homogeneous core/shell ZnO/ZnMgO quantum well heterostructures on vertical ZnO nanowires
B. Q. Cao, J. Zúñiga-Pérez, N. Boukos, C. Czekalla, H. Hilmer, J. Lenzner, A. Travlos, M. Lorenz, and M. Grundmann
Nanotechnology, 20, 305701, (2009) - Papier régulier
 
GaN Quantum Dots Grown on Silicon for Free-Standing Membrane Photonic Structures
Sylvain Sergent, Jean-Christophe Moreno, Eric Frayssinet, Sébastien Chenot, Mathieu Leroux, and Fabrice Semond
Applied Physics Express, 2, 051003, (2009) - Papier régulier
 

Autres Publications :

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Responsable : Jesus Zuniga Perez